A new lightweight, flame-resistant, and super-elastic “metamaterial” has been shown to combine high strength with electrical conductivity and thermal insulation, suggesting potential applications from buildings to aerospace, according to researchers at Purdue University (West Lafayette, Indiana) and several other institutions.
The composite combines nanolayers of a ceramic called aluminum oxide with graphene, an extremely thin sheet of carbon. Although both the ceramic and graphene are brittle, they say the new metamaterial has a honeycomb microstructure that provides stronger elasticity and structural robustness.
Metamaterials are engineered with features, patterns, or elements on the scale of nanometers, or billionths of a meter, providing new properties for various potential applications.
Graphene would ordinarily degrade when exposed to high temperatures, but the ceramic imparts high heat tolerance and flame resistance. These properties could be useful as a heat shield for aircraft, the researchers say, adding that its lightweight, high-strength, and shock-absorbing properties could make the composite a good substrate material for flexible electronic devices and “large strain sensors.”
Because it has high electrical conductivity and yet is an excellent thermal insulator, it might be used as a flame-retardant, thermally insulating coating, as well as sensors and devices that convert heat into electricity, says Gary Cheng, an associate professor at Purdue’s industrial engineering school.
“This material is lighter than a feather,” Cheng says. “The density is really low. It has a very high strength-to-weight ratio.”
The findings were detailed in a research paper published in the journal Advanced Materials. The paper was a collaboration between Purdue, Lanzhou University (Lanzhou, China), the Harbin Institute of Technology (Harbin, China), and the U.S. Air Force Research Laboratory (Riverside, Ohio).
“The outstanding properties of today’s ceramic-based components have been used to enable many multifunctional applications, including thermal protective skins, intelligent sensors, electromagnetic wave absorption, and anticorrosion coatings,” Cheng says.
However, ceramic-based materials have several fundamental bottlenecks that prevent their ubiquitous use as functional or structural elements.
“Here, we report a multifunctional ceramic-graphene metamaterial with microstructure-derived super-elasticity and structural robustness,” Cheng says. “We achieved this by designing a hierarchical honeycomb microstructure assembled with multi-nanolayer cellular walls serving as basic elastic units. This metamaterial demonstrates a sequence of multifunctional properties simultaneously that have not been reported for ceramics and ceramics–matrix–composite structures.”
The composite material is made of interconnected cells of graphene sandwiched between ceramic layers. The graphene scaffold, referred to as an aerogel, is chemically bonded with ceramic layers using a process called atomic layer deposition.
“We carefully control the geometry of this graphene aerogel,” Cheng says. “And then we deposit very thin layers of the ceramic. The mechanical property of this aerogel is multifunctional, which is very important. This work has the potential of making graphene a more functional material.”
The process might be scaled up for industrial manufacturing, he adds.
According to the team, future work will include research to enhance the material’s properties, possibly by changing its crystalline structure, scaling up the process for manufacturing, and controlling the microstructure to tune material properties.
The research was funded in part by the U.S. National Institute of Standards and Technology (Gaithersburg, Maryland).
Source: Purdue University, www.purdue.edu.